Pyrolysis, Gasification, Plasma Arc, Land Filling
……

Challenging Technologies or
Challenged Technologies?
If it sounds too good to be true – it probably is!
Some technologies that fit this criteria are:
Gasification
Pyrolysis,
Plasma Arc
“Water Wash Systems”
Etc…
The idea is to stop land filling and not to continue expensive
experiments!
Outdated Concept:
Worst of the “pack”: Landfilling:
Today the number one competition to WTE is land
filling. WTE and land filling compete in different
areas and on different levels. One can differentiate between region,
governmental regulations, political and public perception, and economic
perception all on a local, state and/or nationwide level.
Today’s landfill practices incorporate “state of the art”
landfill
technology – however, when compared to WRSI’s Advanced Thermal
Recycling (ATR) technology it is completely outdated.
Environmental activists dislike landfills not only because of the
potential for pollution, but because they permanently remove various raw
materials from economic use. All of the energy and natural resources
that went into the manufacturing process of a disposed of item are
"wasted" and not conserved. This is said to contribute to damage of
forests, and agricultural areas, including in less-developed countries
that derive a majority of their export revenues from raw material.
Methane is 21x more potent than CO2
One million tons of Municipal Solid Waste (MSW) treated in a modern
WTE facility and not land filled will release 500,000
tons less CO2 into the atmosphere.
Alternative Technologies for Dealing with MSW:
In addition to landfilling and ATR and conventional
WTE there are two
other technologies available for dealing with MSW: Pyrolysis and
Gasification. Approximately 200 plants and test facilities have been
built in the last twenty years. Very few plants remain in operation
today. These technologies have proven uneconomic and undependable in
dealing with quantities of any consequence. Industry may find solutions
for these technical shortcomings over the next couple of decades,
however at this time their commercial use is limited.
Pyrolysis:
Technical Description: Pyrolysis is used for the conversion of MSW
biomass into liquids. This process burns wet MSW in an oxygen and water
free environment. It generates substantial amounts of condensable
hydrocarbons which make operating the plant difficult and inefficient.
The solids resulting from the Pyrolysis process are highly contaminated
and are high in carbon thus making the solids unsuitable for land
filling without further treatment. Additional processing required
consumes more energy than the Pyrolysis produces, thus negating
commercial viability.
The use of the Pyrolysis condensate from waste Pyrolysis for upgrading
and production of special oils etc. was tested in many different ways.
All failed because inefficient technical performance could not guarantee
the pureness of the product. This resulted in poor economic performance
with the outcome that the operational costs were several times higher
than the gain.
The use of Pyrolysis gas and condensate for thermal use with combustion
needs an additional reactor which adds to the price tag significantly.
Direct combustion is far more efficient
than Pyrolysis.
Remnants still have to be land filled!
Gasification:
Technology Description: Gasification is a process
that uses heat, pressure and steam to convert materials directly into a
gas composed primarily of carbon monoxide and hydrogen. Typical raw
materials used in gasification are coal, petroleum-based materials and
organic materials. The feedstock is prepared and fed, in either dry or
slurried form, into a sealed reactor chamber called a gasifier. Most
commercial gasification technologies do not use oxygen. All require an
energy source to generate heat and begin processing.
Hydrocarbon build up in the flue gas of these
plants is a significant technical problem. This has been the main
contributor to plant failures. Theoretically the power production of a
gasification plant can be higher than that of a combustion plant
although this has never been achieved. This process requires
heterogeneous waste input which means that a great deal of sorting must
be done at the front end. The combined cost of the requirements to
operate gasification has made it commercially unviable.
Unless significant higher fees are paid for the
treatment of waste such as in Japan ($300 to $1000) neither gasification
nor Pyrolysis are economically viable.
Direct combustion is far more efficient than
gasification.
Remnants still have to be land filled!
There are many other technologies that tried and
failed which are discussed in the PowerPoint presentations. These can be
found in numerous places on the website.
Plasma Arc:
Technology Description: Two high voltage probes
create an electrical arc in a field of low pressure gas which causes the
gas molecules to lose an electron and become ionized; the resulting hot,
ionized gas is referred to as a "plasma." When a combination of organic
and inorganic waste is introduced into the plasma field, the intense
heat breaks the waste products’ molecules into simpler compounds. These
gaseous products are then scrubbed to remove contaminants, and burned or
used directly in a gas turbine to produce electricity. The resulting
products from the gas combustion are carbon monoxides, hydrogen and
carbon dioxides from the organic waste and a glassy slag residue from
the inorganic waste. The plasma arc itself operates at a temperature of
7000° F. The reaction chamber heated by the plasma will reach between
1700 and 2200° F. The slag is typically around 3000° F when discharged
from the Pyrolysis chamber.
Technical Pitfalls
-
The electrodes which create
the arc and generate the plasma must be in contact with the solid
waste. The physical characteristics of the waste, as well as the
corrosive gases created as Pyrolysis proceeds leads to a very short
operating life for the electrodes. Thus, reactors must frequently be
removed from service to permit replacement electrodes to be
installed.
-
A tremendous amount of
external, electrical energy is required to operate the arc which
reduces the net positive quantity of electrical output from the
plant.
-
Pre-processing (shredding)
is also a requirement of the plasma arc method with greater
homogeneity and smaller size of the feed to the plasma reactor
decreasing the possibility of fouling or damage of the electrodes
that are inserted into the waste mass to achieve the decomposition
reactions in the waste feed.
-
The high temperature gases
produced from the garbage feed stock can also include vaporized
metals such as cadmium, mercury, and lead. These can be emitted into
the atmosphere following the combustion chamber, internal combustion
engines or gas turbine stage. Rapidly cooling the gas either before
it enters the gas reactor of afterward is the only method of
capturing the metals and converting them back into solid form.
Cooling is difficult given the high temperatures generated by the
plasma arc and, thus plants utilizing this technology face air
pollution control issues. Quick cooling of the flue gases (exit
gases) is also necessary to prohibit the reformulation of dioxins
and furans that are destroyed during the incineration process. The
flue gases must be cooled below 300 degrees F within seconds to
prevent dioxins and furans from forming. The plasma arc system does
not have a boiler which can easily facilitate this rapid cooling and
current designs employ a liquid scrubbing step. There is currently
no data with respect to air quality available for the plasma arc
facilities in operation worldwide.
The bottom line is that none of these
technologies have a proven concept that works with MSW. These
technologies are not laid out to deal with the heterogeneous challenges
of MSW but rather to deal with single a homogenized stream like coal
(and even here many have failed).